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Tuning the electronic structure of NiCoP arrays through V doping for pH-universal hydrogen evolution reaction electrocatalyst

Yu Lin, Jinlei Wang, Duanlin Cao, Yaqiong Gong

《化学科学与工程前沿（英文）》 2021年 第15卷 第5期   页码 1134-1146 doi: 10.1007/s11705-020-2014-x

摘要： The exploration of cost-effective, high-performance, and stable electrocatalysts for the hydrogen evolution reaction (HER) over wide pH range (0–14) is of paramount importance for future renewable energy conversion technologies. Regulation of electronic structure through doping vanadium atoms is a feasible construction strategy to enhance catalytic activities, electron transfer capability, and stability of the HER electrode. Herein, V-doped NiCoP nanosheets on carbon fiber paper (CFP) (denoted as V -NiCoP/CFP) were constructed by doping V modulation on NiCoP nanosheets on CFP and used for pH-universal HER. Benefiting from the abundant catalytic sites and optimized hydrogen binding thermodynamics, the resultant V -NiCoP/CFP demonstrates a significantly improved HER catalytic activity, requiring overpotentials of 46.5, 52.4, and 85.3 mV to reach a current density of 10 mA·cm in 1 mol·L KOH, 0.5 mol·L H SO , and 1 mol·L phosphate buffer solution (PBS) electrolytes, respectively. This proposed cation-doping strategy provides a new inspiration to rationally enhance or design new-type nonprecious metal-based, highly efficient, and pH-universal electrocatalysts for various energy conversion systems.

关键词： hydrogen evolution reaction     transition metal phosphides     pH-universal     vanadium doping     carbon fiber paper    

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Study on the crystal morphology and melting behavior of isothermally crystallized composites of short carbonfiber and poly(trimethylene terephthalate)

Mingtao RUN, Hongzan SONG, Yanping HAO

《化学科学与工程前沿（英文）》 2009年 第3卷 第3期   页码 255-264 doi: 10.1007/s11705-009-0008-9

摘要： The spherulites of the short carbon fiber(SCF)/poly (trimethylene terephthalate) (PTT) composites formed in limited space at designed temperatures, and their melting behaviors were studied by the polarized optical microscopy, atomic force microscopy (AFM), and scanning electron microscopy (SEM), respectively. The results suggest that SCF content, isothermal crystallization temperatures, and the film thicknesses influence the crystal morphology of the composites. The dimension of the spherulites is decreased with increasing SCF content, but whether banded or nonbanded spherulites will form in the composites is not dependent on SCF content. However, the crystal morphology of the composites depends strongly on the temperature. When the isothermal crystallization temperatures increase from 180°C to 230°C, the crystal morphology of SCF/PTT composites continuously changes in the following order: nonbanded → banded → nonbanded spherulites. Discontinuous circle lines form in the film when the film thickness increases from 30 to 60 μm. Basing on the SEM observation, it is found that these circle lines are cracks formed due to the constriction difference of the different parts of the spherulites. These cracks are formed when the film is cooled from the isothermal crystallization temperature to the room temperature at a slow cooling rate; while they will disappear gradually at different temperatures in the heating process. The crack will appear/disappear first around the center of the spherulite when the film was cooled/heated. The nontwisted or slightly twisted lamellas will reorganize to form highly twisted lamellas inducing apparent banded texture of the spherulites.

关键词： poly(trimethylene terephthalate)     short carbon fiber     banded spherulites     crack    

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The preparation and performance of lignin-based activated carbon fiber adsorbents for treating gaseous

Min Song, Wei Zhang, Yongsheng Chen, Jinming Luo, John C. Crittenden

《化学科学与工程前沿（英文）》 2017年 第11卷 第3期   页码 328-337 doi: 10.1007/s11705-017-1646-y

摘要： Two types of lignin-based carbon fibers were prepared by electrospinning method. The first was activated with Fe O (LCF-Fe), and the second was not activated with Fe O (LCF). Gas phase adsorption isotherms for toluene on LCF-Fe and LCF were studied. The gas phase adsorption isotherm for 0% RH showed LCF-Fe have about 439 mg/g adsorption capacity which was close to that of commercially available activated carbon (500 mg/g). The Dubinin-Radushkevich equation described the isotherm data very well. Competitive adsorption isotherms between water vapor and toluene were measured for their RH from 0 to 80%. The effect of humidity on toluene gas-phase adsorption was predicted by using the Okazaki et al. model. In addition, a constant pattern homogeneous surface diffusion model (CPHSDM) was used to predict the toluene breakthrough curve of continuous flow-packed columns containing LCF-Fe, and its capacity was 412 mg/g. Our study, which included material characterization, adsorption isotherms, kinetics, the impact of humidity and fixed bed performance modeling, demonstrated the suitability of lignin-based carbon fiber for volatile organic compound removal from gas streams.

关键词： lignin     carbon fiber     electrospinning     toluene     humidity    

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Experimental and numerical investigations of the compressive behavior of carbon fiber-reinforced polymer-strengthened

Peng DENG, Boyi YANG, Xiulong CHEN, Yan LIU

《结构与土木工程前沿（英文）》 2020年 第14卷 第5期   页码 1215-1231 doi: 10.1007/s11709-020-0663-y

摘要： A method for strengthening damaged tubular steel T-joints under axial compression by wrapping them with carbon fiber-reinforced polymer (CFRP) sheets was proposed and evaluated. The influence of the CFRP strengthening on the failure mode and load capacity of T-joints with different degrees of damage was investigated using experiments and finite element analyses. Five T-joints were physically tested: one bare joint to obtain the peak load and corresponding displacement ( ), two reinforced joints to provide a reference, and two pre-damaged then retrofitted joints to serve as the primary research objects. The ratio of the pre-loaded specimen chord displacement to the value of was considered to be the degree of damage of the two retrofitted joints, and was set to 0.80 and 1.20. The results demonstrate that the maximum capacity of the retrofitted specimen was increased by 0.83%–15.06% over the corresponding unreinforced specimens. However, the capacity of the retrofitted specimen was 2.51%–22.77% lesser compared with that of the directly reinforced specimens. Next, 111 numerical analysis models (0.63≤ ≤0.76, 9.70≤ ≤16.92) were established to parametrically evaluate the effects of different geometric and strengthening parameters on the load capacity of strengthened tubular T-joints under different degrees of damage. The numerical analysis results revealed that the development of equivalent plastic strain at the selected measuring points was moderated by strengthening with CFRP wrapping, and indicated the optimal CFRP strengthening thickness and wrapping orientation according to tubular T-joint parameters. Finally, reasonable equations for calculating the load capacity of CFRP-strengthened joints were proposed and demonstrated to provide accurate results. The findings of this study can be used to inform improved CFRP strengthening of damaged tubular steel structures.

关键词： tubular T-joint     carbon fiber-reinforced polymer     degree of damage     numerical analysis     equivalent plastic strain    

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Effect of denitrifying bacteria on the electrochemical reaction of activated carbon fiber in electrochemical

YING Diwen, JIA Jinping, ZHANG Lehua

《环境科学与工程前沿（英文）》 2007年 第1卷 第3期   页码 305-310 doi: 10.1007/s11783-007-0051-z

摘要： An electrochemical-activated denitrifying biofilm system consisting of activated carbon fiber electrodes immobilized with denitrifying bacteria film as cathode was studied. A revised model for an electrochemical-activated denitrifying biofilm was developed and validated by electrochemical analysis of cathodal polarization curves and nitrate consumption rate. The cathodal polarization curve and nitrate consumption rate were introduced to verify the rate of electrochemical reaction and the activity of denitrifying bacteria, respectively. It was shown that the denitrification process effectively strengthened the electrochemical reaction while the electron also intensified denitrification activity. Electron was transferred between electrochemical process and biological process not only by hydrogen molecule but also by new produced active hydrogen atom. Additionally, a parameter of apparent exchange current density was deprived from the cathodal polarization curve with high overpotential, and a new bio-effect current density was defined through statistical analysis, which was linearly dependent to the activity of denitrification bacteria. Activated carbon fiber (ACF) electrode was also found to be more suitable to the electrochemical denitrifying system compared with graphite and platinum.

关键词： ACF     apparent exchange     hydrogen molecule     activated     biological process    

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Studies of fiber-matrix debonding

Navneet DRONAMRAJU,Johannes SOLASS,Jörg HILDEBRAND

《结构与土木工程前沿（英文）》 2015年 第9卷 第4期   页码 448-456 doi: 10.1007/s11709-015-0316-8

摘要： In this paper, the debonding of a single fiber-matrix system of carbon fiber reinforced composite (CFRP) AS4/Epson 828 material is studied using Cohesive Zone Model (CZM). The effect of parameters namely, maximum tangential contact stress, tangential slip distance and artificial damping coefficient on the debonding length at the interface of the fiber-matrix is analyzed. Contact elements used in the CZM are coupled based on a bilinear stress-strain curve. Load is applied on the matrix, tangential to the interface. Hence, debonding is observed primarily in Mode II. Wide range of values are considered to study the inter-dependency of the parameters and its effect on debonding length. Out of the three parameters mentioned, artificial damping coefficient and tangential slip distance significantly affect debonding length. A thorough investigation is recommended for case wise interface debonding analysis, to estimate the optimal parametric values while using CZM.

关键词： single fibre     cohesive zone model     interface debonding     carbon fiber reinforced composite (CFRP)    

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Consumption of carbon fiber plates in the reinforced concrete beams strengthened with CFPs

BU Liangtao, SHI Chuxian, SONG Li

《结构与土木工程前沿（英文）》 2007年 第1卷 第4期   页码 393-398 doi: 10.1007/s11709-007-0053-8

摘要： Four-point bending flexural tests were conducted to one full-size reinforced concrete (RC) beam and three full-size RC beams strengthened with carbon fiber plates (CFPs). The experimental results showed that the consumption of CFP

关键词： flexural     full-size     Four-point     consumption     experimental    

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Shear behavior of ultra-high-performance concrete beams prestressed with external carbon fiber-reinforced

《结构与土木工程前沿（英文）》 2021年 第15卷 第6期   页码 1426-1440 doi: 10.1007/s11709-021-0783-z

摘要： The ultra-high-performance concrete (UHPC) and fiber-reinforced polymer (FRP) are well-accepted high-performance materials in the field of civil engineering. The combination of these advanced materials could contribute to improvement of structural performance and corrosion resistance. Unfortunately, only limited studies are available for shear behavior of UHPC beams reinforced with FRP bars, and few suggestions exist for prediction methods for shear capacity. This paper presents an experimental investigation on the shear behavior of UHPC beams reinforced with glass FRP (GFRP) and prestressed with external carbon FRP (CFRP) tendons. The failure mode of all specimens with various shear span to depth ratios from 1.7 to 4.5 was diagonal tension failure. The shear span to depth ratio had a significant influence on the shear capacity, and the effective prestressing stress affected the crack propagation. The experimental results were then applied to evaluate the equations given in different codes/recommendations for FRP-reinforced concrete structures or UHPC structures. The comparison results indicate that NF P 18-710 and JSCE CES82 could appropriately estimate shear capacity of the slender specimens with a shear span to depth ratio of 4.5. Further, a new shear design equation was proposed to take into account the effect of the shear span to depth ratio and the steel fiber content on shear capacity.

关键词： beam     external prestressing     ultra-high-performance concrete     fiber-reinforced polymers     shear behavior     design equation    

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A Cu-modified active carbon fiber significantly promoted HS and PH simultaneous removal at a low reaction

《环境科学与工程前沿（英文）》 2021年 第15卷 第6期 doi: 10.1007/s11783-021-1425-3

摘要：

• Cu0.15-ACF performs the best for H2S and PH3 simultaneous removal.

关键词： ACF     H2S     PH3     Cu     Low temperature     Simultaneous removal    

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Review on cellulose paper-based electrodes for sustainable batteries with high energy densities

《化学科学与工程前沿（英文）》 2023年 第17卷 第8期   页码 1010-1027 doi: 10.1007/s11705-023-2307-y

摘要： Powering the future, while maintaining strong socioeconomic growth and a cleaner environment, is going to be one of the biggest challenges faced by mankind nowadays. Thus, there is a transition from the use of fossil fuels to renewable energy sources. Cellulose, the main component of paper, represents a unique type of bio-based building blocks featuring exciting properties: low-cost, hierarchical fibrous structures, hydrophilicity, biocompatible, mechanical flexibility, and renewability, which make it perfect for use in paper-based sustainable energy storage devices. This review focuses on lithium-ion battery application of celluloses with cellulose at different scales, i.e., cellulose microfibers, and nanocellulose, and highlights the new trends in the field. Recent advances and approaches to construct high mass loading paper electrodes toward high energy density batteries are evaluated and the limitations of paper-based cathodes are discussed. This will stimulate the use of natural resources and thereby the development of renewable electric energy systems based on sustainable technologies with low environmental impacts and carbon footprints.

关键词： cellulose     paper electrodes     Li-ion batteries     high energy density    

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Experimental study on fire protection methods of reinforced concrete beams strengthened with carbon fiber

HU Kexu, HE Guisheng, LU Fan

《结构与土木工程前沿（英文）》 2007年 第1卷 第4期   页码 399-404 doi: 10.1007/s11709-007-0054-7

摘要： In this paper, two reinforced concrete (RC) beams strengthened with carbon fiber reinforced polymer (CFRP) and attached with thick-painted fire resistant coating were tested for fire resistance following the standard fire testing procedures. The experimental results show that the specimen pasted with the insulated layer of 50 mm in thickness could resist fire for 2.5 h. It is also demonstrated that the steel wire mesh embedded in the insulated layer can effectively prevent it from cracking and eroding under firing.

关键词： polymer     insulated     resistant     CFRP     resistance    

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Multiscale model of micro curing residual stress evolution in carbon fiber-reinforced thermoset polymer

Xinyu HUI, Yingjie XU, Weihong ZHANG

《机械工程前沿（英文）》 2020年 第15卷 第3期   页码 475-483 doi: 10.1007/s11465-020-0590-6

摘要： In this study, the micro curing residual stresses of carbon fiber-reinforced thermoset polymer (CFRP) composites are evaluated using a multiscale modeling method. A thermochemical coupling model is developed at the macroscale level to obtain the distributions of temperature and degree of cure. Meanwhile, a representative volume element model of the composites is established at the microscale level. By introducing the information from the macroscale perspective, the curing residual stresses are calculated using the microscale model. The evolution of curing residual stresses reveals the interaction mechanism of fiber, matrix, and interphase period during the curing process. Results show that the curing residual stresses mostly present a tensile state in the matrix and a compressive state in the fiber. Furthermore, the curing residual stresses at different locations in the composites are calculated and discussed. Simulation results provide an important guideline for the analysis and design of CFRP composite structures.

关键词： CFRP     curing residual stress     multiscale modeling     finite element method    

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Strengthening of reinforced concrete beams using fiber-reinforced cementitious matrix systems fabricated

《结构与土木工程前沿（英文）》   页码 1100-1116 doi: 10.1007/s11709-023-0967-9

摘要： The performance of a new fiber-reinforced cementitious matrix (FRCM) system developed using custom-designed mortar and fabrics is investigated in this study. The behavior of this system is evaluated in terms of both the flexural and shear strengthening of reinforced concrete beams. Eight beams are designed to assess the effectiveness of the FRCM system in terms of flexural strengthening, and four specimens are designed to investigate their shear behavior. The parameters investigated for flexural strengthening are the number of layers, span/depth ratio, and the strengthening method. Unlike previous studies, custom fabrics with similar axial stiffness are used in all strengthening methods in this study. In the shear-strengthened specimens, the effects of the span/depth ratio and strengthening system type (fiber-reinforced polymer (FRP) or FRCM) are investigated. The proposed FRCM system exhibits desirable flexural and shear strengthening for enhancing the load capacity, provides sufficient bonding with the substrate, and prevents premature failure modes. Considering the similar axial stiffness of fabrics used in both FRCM and FRP systems and the higher load capacity of specimens strengthened by the former, cement-based mortar performs better than epoxy.

关键词： fiber-reinforced cementitious matrix     flexural strengthening     shear strengthening     carbon fiber-reinforced polymer     shear span    

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Research progress on low dielectric constant modification of cellulose insulating paper for power transformers

《化学科学与工程前沿（英文）》 2023年 第17卷 第8期   页码 991-1009 doi: 10.1007/s11705-022-2259-7

摘要： Because of the increase in the transmission voltage levels, the demand for insulation reliability of power transformers has increasingly become critical. Cellulose insulating paper is the main insulating component of power transformers. To improve the insulation level of ultrahigh voltage transformers and reduce their weight and size, reducing the dielectric constant of oil-immersed cellulose insulating paper is highly desired. Cellulose is used to produce power-transformer insulating papers owing to its excellent electrical properties, renewability, biodegradability and abundance. The dielectric constant of a cellulose insulating paper can be effectively reduced by chemical or physical modification. This study presents an overview of the foreign and domestic research status of the use of modification technology to reduce the dielectric constant of cellulose insulating papers. All the mentioned methods are analyzed in this study. Finally, some recommendations for future modified cellulose insulating paper research and applications are proposed. This paper can provide a reference for further research on low dielectric constant cellulose insulating paper in the future.

关键词： low dielectric constant     chemical and physical modification     cellulose insulating paper     transformer     nanomaterials.    

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Hole quality in longitudinal–torsional coupled ultrasonic vibration assisted drilling of carbon fiber

Guofeng MA, Renke KANG, Zhigang DONG, Sen YIN, Yan BAO, Dongming GUO

《机械工程前沿（英文）》 2020年 第15卷 第4期   页码 538-546 doi: 10.1007/s11465-020-0598-y

摘要： Carbon fiber reinforced plastic (CFRP) composites are extremely attractive in the manufacturing of structural and functional components in the aircraft manufacturing field due to their outstanding properties, such as good fatigue resistance, high specific stiffness/strength, and good shock absorption. However, because of their inherent anisotropy, low interlamination strength, and abrasive characteristics, CFRP composites are considered difficult-to-cut materials and are prone to generating serious hole defects, such as delamination, tearing, and burrs. The advanced longitudinal–torsional coupled ultrasonic vibration assisted drilling (LTC-UAD) method has a potential application for drilling CFRP composites. At present, LTC-UAD is mainly adopted for drilling metal materials and rarely for CFRP. Therefore, this study analyzes the kinematic characteristics and the influence of feed rate on the drilling performance of LTC-UAD. Experimental results indicate that LTC-UAD can reduce the thrust force by 39% compared to conventional drilling. Furthermore, LTC-UAD can decrease the delamination and burr factors and improve the surface quality of the hole wall. Thus, LTC-UAD is an applicable process method for drilling components made with CFRP composites.

关键词： longitudinal–torsional coupled     ultrasonically drilling     CFRP     thrust force     hole quality    

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标题 作者 时间 类型 操作

Tuning the electronic structure of NiCoP arrays through V doping for pH-universal hydrogen evolution reaction electrocatalyst

Yu Lin, Jinlei Wang, Duanlin Cao, Yaqiong Gong

期刊论文

Study on the crystal morphology and melting behavior of isothermally crystallized composites of short carbonfiber and poly(trimethylene terephthalate)

Mingtao RUN, Hongzan SONG, Yanping HAO

期刊论文

The preparation and performance of lignin-based activated carbon fiber adsorbents for treating gaseous

Min Song, Wei Zhang, Yongsheng Chen, Jinming Luo, John C. Crittenden

期刊论文

Experimental and numerical investigations of the compressive behavior of carbon fiber-reinforced polymer-strengthened

Peng DENG, Boyi YANG, Xiulong CHEN, Yan LIU

期刊论文

Effect of denitrifying bacteria on the electrochemical reaction of activated carbon fiber in electrochemical

YING Diwen, JIA Jinping, ZHANG Lehua

期刊论文

Studies of fiber-matrix debonding

Navneet DRONAMRAJU,Johannes SOLASS,Jörg HILDEBRAND

期刊论文

Consumption of carbon fiber plates in the reinforced concrete beams strengthened with CFPs

BU Liangtao, SHI Chuxian, SONG Li

期刊论文

Shear behavior of ultra-high-performance concrete beams prestressed with external carbon fiber-reinforced

期刊论文

A Cu-modified active carbon fiber significantly promoted HS and PH simultaneous removal at a low reaction

期刊论文

Review on cellulose paper-based electrodes for sustainable batteries with high energy densities

期刊论文

Experimental study on fire protection methods of reinforced concrete beams strengthened with carbon fiber

HU Kexu, HE Guisheng, LU Fan

期刊论文

Multiscale model of micro curing residual stress evolution in carbon fiber-reinforced thermoset polymer

Xinyu HUI, Yingjie XU, Weihong ZHANG

期刊论文

Strengthening of reinforced concrete beams using fiber-reinforced cementitious matrix systems fabricated

期刊论文

Research progress on low dielectric constant modification of cellulose insulating paper for power transformers

期刊论文

Hole quality in longitudinal–torsional coupled ultrasonic vibration assisted drilling of carbon fiber

Guofeng MA, Renke KANG, Zhigang DONG, Sen YIN, Yan BAO, Dongming GUO

期刊论文